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/ 2002
/ July
/ Thursday, July 11, 2002
[Federal Register: July 11, 2002 (Volume 67, Number 133)]
[Proposed Rules]
[Page 46027-46088]
From the Federal Register Online via GPO Access [wais.access.gpo.gov]
[DOCID:fr11jy02-24]
[[Page 46027]]
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Part II
Environmental Protection Agency
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40 CFR Part 63
National Emission Standards for Hazardous Air Pollutants: Printing,
Coating, and Dyeing of Fabrics and Other Textiles; Proposed Rule
[[Page 46028]]
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ENVIRONMENTAL PROTECTION AGENCY
40 CFR Part 63
[FRL-7237-1]
RIN 2060-AG98
National Emission Standards for Hazardous Air Pollutants:
Printing, Coating, and Dyeing of Fabrics and Other Textiles
AGENCY: Environmental Protection Agency (EPA).
ACTION: Proposed rule.
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SUMMARY: This action proposes national emission standards for hazardous
air pollutants (NESHAP) for fabric and other textile coating, printing,
slashing, dyeing, and finishing operations, pursuant to section 112(d)
of the Clean Air Act (CAA). This action also revises the title of the
source category. The Printing, Coating and Dyeing of Fabrics source
category was included in the initial list of categories of hazardous
air pollutants (HAP), published in the Federal Register on July 16,
1992. This action changes the title of the source category to Printing,
Coating, and Dyeing of Fabrics and Other Textiles, to clarify the
applicability of the proposed NESHAP to HAP-emitting operations
performed on textile substrates including, but not limited to, fabric.
The EPA has estimated that there are approximately 135 major source
facilities in the Printing, Coating, and Dyeing of Fabrics and Other
Textiles source category. The principal HAP emitted by these affected
sources include toluene, methyl ethyl ketone (MEK), methanol, xylenes,
methyl isobutyl ketone (MIBK), methylene chloride, n-hexane,
trichloroethylene, and n,n-dimethyl formamide. Secondary HAP emitted
include 1,1,1-trichloroethane, naphthalene, ethyl benzene, glycol
ethers (ethylene glycol), biphenyl, and styrene.
Exposure to these substances has been demonstrated to cause adverse
health effects such as irritation of the eye, lung, and mucous
membranes, effects on the central nervous system, and damage to the
liver. The EPA has classified two of the HAP as probable or possible
human carcinogens. In general, these adverse health effect findings
have only been shown with concentrations higher than those typically in
the ambient air. The proposed standards would reduce nationwide HAP
emissions from major sources by approximately 60 percent. The reduction
in HAP emissions would be achieved by requiring all fabric and other
textiles coating, printing, slashing, dyeing, and finishing operations
at major sources to meet the HAP emission standards reflecting the
application of the maximum achievable control technology (MACT).
Emission reductions achieved by these standards, when combined with the
emission reductions achieved by other similar standards, would protect
and enhance the quality of the Nation's air resources so as to promote
the public health and welfare, protect the environment, and achieve a
primary goal of the CAA.
DATES: Comments. Submit comments on or before September 9, 2002.
Public Hearing. If anyone contacts the EPA requesting to speak at a
public hearing, they should do so by July 31, 2002. If requested, a
public hearing will be held within approximately 30 days following
publication of this document in the Federal Register.
ADDRESSES: Comments. By U.S. Postal Service, send comments (in
duplicate if possible) to: Air and Radiation Docket and Information
Center (6102), Attention Docket Number A-97-51, U.S. EPA, 1200
Pennsylvania Avenue, NW., Washington, DC 20460. In person or by
courier, deliver comments (in duplicate if possible) to: Air and
Radiation Docket and Information Center (6102), Attention Docket Number
A-97-51, U.S. EPA, 501 M Street, SW., Room M-1500, Washington, DC
20460. The EPA requests a separate copy also be sent to the contact
person listed in FOR FURTHER INFORMATION CONTACT.
Public Hearing. If a public hearing is held, it will be held at the
new EPA facility complex in Research Triangle Park, North Carolina. You
should contact Ms. Janet Eck, Coatings and Consumer Products Group
(C539-03), Emission Standards Division, U.S. EPA, Research Triangle
Park, NC 27711, telephone number (919) 541-7946, to request to speak at
a public hearing or to find out if a hearing will be held.
Docket. Docket No. A-97-51 contains supporting information used in
developing the proposed standards. The docket is located at the U.S.
EPA, 401 M Street, SW., Washington, DC 20460 in Room M-1500, Waterside
Mall (ground floor), and may be inspected from 8:30 a.m. to 5:30 p.m.,
Monday through Friday, excluding legal holidays.
FOR FURTHER INFORMATION CONTACT: Mr. Vinson Hellwig, Coatings and
Consumer Products Group (C539-03), Emission Standards Division, U.S.
EPA, Research Triangle Park, NC 27711; telephone number (919) 541-2317;
facsimile number (919) 541-5689; electronic mail (e-mail) address:
hellwig.vinson@epa.gov.
SUPPLEMENTARY INFORMATION: Comments. Comments and data may be submitted
by e-mail to: a-and-r-docket@epa.gov. Electronic comments must be
submitted as an ASCII file to avoid the use of special characters and
encryption problems and will also be accepted on disks in
WordPerfect file format. All comments and data submitted in
electronic form must note the docket number: A-97-51. No confidential
business information (CBI) should be submitted by e-mail. Electronic
comments may be filed online at many Federal Depository Libraries.
Commenters wishing to submit proprietary information for
consideration must clearly distinguish such information from other
comments and clearly label it as CBI. Send submissions containing such
proprietary information directly to the following address, and not to
the public docket, to ensure that proprietary information is not
inadvertently placed in the docket: Mr. Vinson Hellwig, c/o OAQPS
Document Control Officer (C404-02), U.S. EPA, Research Triangle Park,
NC 27711. The EPA will disclose information identified as CBI only to
the extent allowed by the procedures set forth in 40 CFR part 2. If no
claim of confidentiality accompanies a submission when it is received
by EPA, the information may be made available to the public without
further notice to the commenter.
Public Hearing. Persons interested in presenting oral testimony or
inquiring as to whether a hearing is to be held should contact Ms.
Janet Eck, Coatings and Consumer Products Group (C539-03), Emission
Standards Division, U.S. EPA, Research Triangle Park, NC 27711;
telephone number (919) 541-7946 at least 2 days in advance of the
public hearing. Persons interested in attending the public hearing
should also contact Ms. Eck to verify the time, date, and location of
the hearing. The public hearing will provide interested parties the
opportunity to present data, views, or arguments concerning these
proposed emission standards.
Docket. The docket is an organized and complete file of all the
information considered by EPA in the development of this rulemaking.
The docket is a dynamic file because material is added throughout the
rulemaking process. The docketing system is intended to allow members
of the public and industries involved to readily identify and locate
documents so that they can effectively participate in the rulemaking
process. Along with the proposed and promulgated standards and their
preambles, the contents of the docket
[[Page 46029]]
will serve as the record in the case of judicial review. (See section
307(d)(7)(A) of the CAA.) The regulatory text and other materials
related to this rulemaking are available for review in the docket or
copies may be mailed on request from the Air and Radiation Docket and
Information Center by calling (202) 260-7548. A reasonable fee may be
charged for copying docket materials.
WorldWide Web (WWW). In addition to being available in the docket,
an electronic copy of the proposed rule will also be available on the
WWW through the Technology Transfer Network (TTN). Following signature
by the EPA Administrator, a copy of the proposed rule will be posted on
the TTN's policy and guidance page for newly proposed or promulgated
rules at http://www.epa.gov/ttn/oarpg. The TTN provides information and
technology exchange in various areas of air pollution control. If more
information regarding the TTN is needed, call the TTN HELP line at
(919) 541-5384.
Regulated Entities. The proposed source category definition
includes sources that engage in the coating, printing, slashing,
dyeing, or finishing of any fabric or other textile. In general,
sources that engage in fabric and other textiles coating, printing,
slashing, dyeing, or finishing operations are covered under the North
American Industrial Classification System (NAICS) codes listed in the
following table. However, sources classified under other NAICS codes
may be subject to the proposed standards if they meet the applicability
criteria. Not all sources classified under the NAICS codes in the
following table will be subject to the proposed standards because some
of the classifications cover products outside the scope of the NESHAP
for printing, coating and dyeing of fabrics and other textiles.
Table 1.--Categories and Entities Potentially Regulated by the Proposed Standards
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NAICS Code NAICS product description
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31321............................................... Broadwoven Fabric Mills
31322............................................... Narrow Fabric Mills and Schiffli Machine Embroidery
313241.............................................. Weft Knit Fabric Mills
313311.............................................. Broadwoven Fabric Finishing Mills
313312.............................................. Textile and Fabric Finishing (except Broadwoven Fabric)
Mills
313320.............................................. Fabric Coating Mills
314110.............................................. Carpet and Rug Mills
326220.............................................. Rubber and Plastics Hoses and Belting and Manufacturing
339991.............................................. Gasket, Packing, and Sealing Device Manufacturing
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This table is not intended to be exhaustive, but rather provides a
guide for readers regarding entities likely to be regulated by this
action. To determine whether your operation is regulated by this
action, you should examine the applicability criteria in Sec. 63.4281
of the proposed rule. If you have any questions regarding the
applicability of this action to a particular entity, consult the person
listed in the preceding FOR FURTHER INFORMATION CONTACT section.
Outline. The information presented in this preamble is organized as
follows:
I. Background
A. What is the source of authority for development of NESHAP?
B. What criteria are used in the development of NESHAP?
C. What are the health effects associated with HAP emissions
from coating, printing, slashing, dyeing, and finishing operations?
II. Summary of the Proposed Rule
A. What source categories and subcategories are affected by the
proposed rule?
B. What is the relationship to other rules?
C. What are the primary sources of emissions and what are the
emissions?
D. What is the affected source?
E. What are the emission limits, operating limits, and other
standards?
F. What are the testing and initial compliance requirements?
G. What are the continuous compliance provisions?
H. What are the notification, recordkeeping, and reporting
requirements?
III. Rationale for Selecting the Proposed Standards
A. How did we select the source category and subcategories?
B. How did we select the regulated pollutants?
C. How did we select the affected source?
D. How did we determine the basis and level of the proposed
standards for existing and new or reconstructed sources?
E. How did we select the format of the proposed standards?
F. How did we select the testing and initial compliance
requirements?
G. How did we select the continuous compliance requirements?
H. How did we select the notification, recordkeeping, and
reporting requirements?
I. How did we select the compliance date?
IV. Summary of Environmental, Energy, and Economic Impacts
A. What are the air impacts?
B. What are the cost impacts?
C. What are the economic impacts?
D. What are the non-air health, environmental, and energy
impacts?
V. Administrative Requirements
A. Executive Order 12866, Regulatory Planning and Review
B. Executive Order 13132, Federalism
C. Executive Order 13175, Consultation and Coordination with
Indian Tribal Governments
D. Executive Order 13045, Protection of Children from
Environmental Health Risks and Safety Risks
E. Executive Order 13211, Actions Concerning Regulations That
Significantly Affect Energy Supply, Distribution, or Use
F. Unfunded Mandates Reform Act of 1995
G. Regulatory Flexibility Act (RFA), as Amended by the Small
Business Regulatory Enforcement Fairness Act of 1996 (SBREFA), 5
U.S.C. 601, et seq.
H. Paperwork Reduction Act
I. National Technology Transfer and Advancement Act
I. Background
A. What Is the Source of Authority for Development of NESHAP?
Section 112 of the CAA requires us to list categories and
subcategories of major sources and area sources of HAP and to establish
NESHAP for the listed source categories and subcategories. The
Printing, Coating, and Dyeing of Fabrics source category was listed on
July 16, 1992 (57 FR 31576) under the Surface Coating Processes
industry group. As has been noted previously in this preamble, today's
action changes the title of the source category to Printing, Coating,
and Dyeing of Fabrics and Other Textiles.
Major sources of HAP are those that have the potential to emit
greater than 10 tons per year (tpy) of any one HAP or 25 tpy of any
combination of HAP.
[[Page 46030]]
B. What Criteria Are Used in the Development of NESHAP?
Section 112 of the CAA requires that we establish NESHAP for the
control of HAP from both new and existing major sources. The CAA
requires the NESHAP to reflect the maximum degree of reduction in
emissions of HAP that is achievable. This level of control is commonly
referred to as the MACT.
The MACT floor is the minimum control level allowed for NESHAP and
is defined under section 112(d)(3) of the CAA. In essence, the MACT
floor ensures that the standard is set at a level that assures that all
major sources achieve the level of control already achieved by the
better-controlled and lower-emitting sources in each source category or
subcategory. For new sources, the MACT standards cannot be less
stringent than the emission control that is achieved in practice by the
best-controlled similar source. The MACT standards for existing sources
can be less stringent than standards for new sources, but they cannot
be less stringent than the average emission limitation achieved by the
best-performing 12 percent of existing sources in the category or
subcategory (or the best-performing five sources for categories or
subcategories with fewer than 30 sources).
In developing MACT, we also consider control options that are more
stringent than the floor. We may establish standards more stringent
than the floor based on the consideration of the cost of achieving the
emissions reductions, any non-air health and environmental impacts, and
energy requirements.
C. What Are the Health Effects Associated With HAP Emissions From
Coating, Printing, Slashing, Dyeing, and Finishing Operations?
The HAP emitted from coating, printing, slashing, dyeing, and
finishing operations include toluene, MEK, methanol, xylenes, MIBK,
methylene chloride, n-hexane, trichloroethylene, and n,n-
dimethylformamide. These compounds account for about 81 percent of the
nationwide HAP emissions from this source category. The HAP that would
be controlled with the proposed rule are associated with a variety of
adverse health effects. These adverse health effects include chronic
health disorders (e.g., irritation of the eyes, lungs, and mucous
membranes, effects on the central nervous system, and damage to the
heart and liver) and acute health disorders (e.g., respiratory
irritation and central nervous system effects such as drowsiness,
headache, and nausea). The EPA has classified two of the HAP (methylene
chloride and naphthalene) as probable or possible human carcinogens.
We do not have the type of current detailed data on each of the
facilities covered by the emission standards for this source category,
and the people living around the affected facilities, that would be
necessary to conduct an analysis to determine the actual population
exposures to the HAP emitted from these affected facilities and
potential for resultant health effects. Therefore, we do not know the
extent to which the adverse health effects described above occur in the
populations surrounding these affected facilities. However, to the
extent the adverse effects do occur, the proposed rule would reduce
emissions and subsequent exposures.
II. Summary of the Proposed Rule
A. What Source Categories and Subcategories Are Affected by the
Proposed Rrule?
The proposed rule would apply to you if you own or operate a fabric
or other textile coating, printing, slashing, dyeing, or finishing
operation or group of such operations that is a major source, or is
located at a major source, or is part of a major source of HAP
emissions, whether or not you manufacture the substrate. The coating,
printing, slashing, dyeing, or finishing operations themselves are not
required to be major sources of HAP emissions in order for them to be
covered by the proposed rule. As long as some part of the facility
where the operations are located (e.g., a process boiler or
manufacturing operations associated with production of the final
product) causes it to be a major source, the coating, printing,
slashing, dyeing, and finishing operations would be subject to the
standards.
Any major HAP-emitting facility that performs coating, printing,
slashing, dyeing, or finishing of fabric or other textiles is in this
source category. As defined in the proposed rule, fabric or other
textiles includes, but is not limited to, yarn, fiber, cord, thread,
fabric and textile products, tents, roofing, soft baggage, marine
fabric, drapery linings, flexible hoses, hot-air balloons, and awnings.
The source category includes three subcategories (coating and printing,
slashing, and dyeing and finishing) as described in the following
paragraphs.
The coating and printing subcategory encompasses coating activities
and equipment used to apply semi-liquid coating material to one or both
sides of a textile web substrate. Once the coating is dried (and cured,
if necessary) it bonds with the substrate to form a continuous solid
film for decorative, protective, or functional purposes. Similarly, the
coating and printing subcategory includes printing activities and
equipment used to apply color and patterns to textile substrates,
usually in the form of a paste. After application of the printing
material, the substrate is treated with steam, heat, or chemicals to
fix the color. If you coat fabric or other textiles and any other
substrate on a coating line, then that line would be subject to the
proposed rule unless it is specifically exempted in another NESHAP. We
currently plan to provide such an exemption in the tire cord production
NESHAP for tire cord coating lines that occasionally coat fabric.
Another exemption is planned for the paper and other web coating NESHAP
for lines that coat medical tape or duct tape.
The slashing subcategory includes the yarn preparation process
performed on warp yarn prior to weaving. Slashing is the application of
a chemical solution (known as sizing) to a yarn in a water solution
followed by squeezing and drying.
The dyeing and finishing subcategory includes the equipment and
operations involved in two separate but related processes that are both
performed at some sources, while only one or the other is performed at
other sources. Dyes and finishes are applied to yarn, fiber, cord,
thread, or fabric in aqueous solutions and then dried. Dyeing is the
application of color to the whole body of a textile substrate.
Finishing is a process performed after dyeing that improves the
appearance and/or usefulness of a textile substrate.
You would not be subject to the proposed rule if your coating,
printing, slashing, dyeing, or finishing operation is located at an
area source. An area source of HAP is any facility that has the
potential to emit HAP but is not a major source. You may establish area
source status by limiting the source's potential to emit HAP through
appropriate mechanisms available through your permitting authority.
Exclusions from the source category include coating, printing,
slashing, dyeing or finishing at sources using only coating, printing,
slashing, dyeing, finishing, thinning, and cleaning materials that
contain no organic HAP; coating, printing, slashing, dyeing, or
finishing that occurs at research or laboratory facilities or that is
part of janitorial, building, and facility maintenance operations; and
coating, printing, slashing, dyeing, or finishing
[[Page 46031]]
used by an affected source and not for commerce, unless organic HAP
emissions from the facility that performs coating, printing, slashing,
dyeing, or finishing operations are as high as the specified major
source HAP emissions.
B. What Is the Relationship to Other Rules?
Affected sources subject to the proposed rule may also be subject
to other rules. We specifically request comments on how monitoring,
recordkeeping, and reporting requirements can be consolidated for
sources that are subject to more than one rule.
New Source Performance Standards--40 CFR part 60, subpart VVV. The
new source performance standards (NSPS) for polymeric coating of
supporting substrates apply to affected facilities that apply
elastomers, polymers, or prepolymers to a supporting web other than
paper, plastic film, metallic foil, or metal coil and that began
construction, reconstruction, or modification after April 30, 1987. The
pollutants regulated are volatile organic compounds (VOC). The affected
facility is each coating operation and any onsite coating mix
preparation equipment used to prepare coatings for the polymeric
coating of the affected substrate. Emissions of VOC from the coating
operation must be reduced by at least 90 percent or a total enclosure
must be installed around the coating operation vented to an add-on
control device that is at least 95 percent efficient. Depending on
criteria in the NSPS, VOC emissions from onsite coating mix preparation
equipment must be vented to a 95 percent efficient add-on control
device or each piece of mix preparation equipment must be covered.
The proposed requirements for coating operations differ from the
NSPS in three ways. First, the ``affected source'' for the proposed
rule is defined broadly as the collection of all of the coating and
printing operations and associated processes at the facility, whereas
the ``affected facility'' for the NSPS is defined narrowly as each
individual coating operation. The proposed NESHAP's broader definition
of an affected source allows averaging across coating and printing
lines for compliance purposes. Second, the proposed rule regulates
organic HAP. While most organic HAP emitted from coating and printing
operations are VOC, some VOC are not listed as HAP, and, therefore, the
NSPS regulates a broader range of pollutants than the proposed NESHAP.
Third, the HAP emission limitations in the proposed rule are in terms
of an overall control efficiency (OCE) with an alternative weight
fraction of solids applied emission rate limit based on the amount of
coating solids used at the affected source. The VOC limitations in the
NSPS are emission reduction standards; there is not an emission rate
option based on the amount of coating solids used. Because of the
differences between the two rules, compliance with either rule cannot
be deemed compliance with the other. A coating or printing operation
that meets the applicability requirements of both rules must comply
with both. Overlapping reporting, recordkeeping, and monitoring
requirements may be resolved through your title V permit.
Future national emission standards for the surface coating of paper
and other web products. The paper and other web coating NESHAP were
proposed September 13, 2000 (65 FR 55332). If you operate a coating
line(s) that applies coatings both to paper and other web and to fabric
and other textile substrates on the same line, then the coating line(s)
is subject to the proposed printing, coating, and dyeing of fabrics and
other textiles NESHAP. The only exceptions are where the paper and
other web substrate being coated is medical tape or duct tape or where
fabric is being laminated to a paper or other web substrate, and these
exceptions will be specified in the paper and other web NESHAP.
Future national emission standards for tire manufacturing. The EPA
has identified affected sources in the tire manufacturing source
category that coat tire cord and that also sometimes apply coatings to
textile cord used in the production of belts and hoses. If the source
is subject to the tire manufacturing NESHAP, it is not subject to the
proposed printing, coating, and dyeing of fabrics and other textiles
NESHAP.
C. What Are the Primary Sources of Emissions and What Are the
Emissions?
HAP emission sources. Coating and printing material application and
curing are the largest contributors of HAP emissions at coating and
printing affected sources. For example, based on the responses to a
survey of the coating industry, the portion of total affected source
HAP emissions attributed to coating application and curing is estimated
to be approximately 95 percent. Other operations and activities that
may create HAP emissions associated with coating/printing include
storage tanks, substrate preparation, coating and printing material
mixing/thinning operations, parts and equipment cleaning, and waste and
wastewater operations.
The primary source of HAP emissions from slashing is methanol from
polyvinyl alcohol (PVA) size, typically applied to synthetics (although
it adheres to and is used for natural fibers as well). The methanol is
present in the PVA size as a contaminant and is not needed for the
slashing process. The methanol emissions can arise either from the size
cooking operation and/or from the application or slashing process--the
distribution is unclear, although it will depend upon the temperature
at which the size is cooked, the cooking time, and how often mixing
containers (cookers) are opened.
The sources of HAP emissions from dyeing are the HAP constituents
that are contained in dyestuffs and auxiliary chemicals as purchased.
The HAP constituents are needed to impart certain desirable
characteristics to the dyed substrate (e.g., certain colors can only be
attained through the use of HAP-containing dyestuffs or auxiliaries.)
No HAP are known to be added by the users. The fraction of HAP
contained in dye materials that is emitted to the atmosphere is
generally estimated to range from zero to 10 percent, although a few
sources report from 19 percent to as much as 100 percent emitted. The
fraction of HAP in dye materials emitted to the atmosphere depends on
the characteristics of the specific HAP constituents and the pressures
and temperatures that the HAP are exposed to in the dyeing process
operations. Most HAP constituents are believed to be rinsed from the
substrate before the substrate is dried, because drying a substrate
with unattached dye would adversely affect the quality of the dyed
product.
The sources of HAP emissions from finishing are the HAP
constituents that are contained in finishing materials as purchased,
i.e., as delivered to the affected source, before alteration. As is the
case with dyeing, the HAP constituents are needed to impart certain
desirable characteristics to the finished substrate (e.g., a resin
finish containing HAP might be applied to a cotton/polyester blend for
durable press and dimensional stability). No HAP are known to be added
by the users. In finishing, unlike in dyeing, the fraction of HAP
contained in finishes that is emitted to the atmosphere is generally
assumed to be 100 percent with the exception of HAP that cross-link to
the fiber, such as formaldehyde. This is because finished textiles are
generally dried and cured at relatively high temperatures over 300
degrees Fahrenheit.
[[Page 46032]]
Organic HAP. Available emission data collected during the
development of the proposed NESHAP show that the primary organic HAP
emitted from coating and printing include toluene, MEK, hexane, and
n,n-dimethylformamide. These compounds account for approximately 92
percent of this subcategory's nationwide organic HAP emissions. Other
significant organic HAP identified include MIBK, hexane, and methylene
chloride.
Available emission data collected during the development of the
proposed NESHAP show that the organic HAP emitted from slashing is
methanol. Methanol accounts for almost 100 percent of this
subcategory's nationwide organic HAP emissions.
Based on emission data reported in survey responses collected
during the development of the proposed NESHAP, methanol, glycol ether,
and ethylene glycol are the primary HAP emitted from textile dyeing and
finishing operations. These HAP account for approximately 82 percent of
this subcategory's nationwide HAP emissions. Other significant organic
HAP identified include formaldehyde, toluene and styrene.
Inorganic HAP. Based on information reported in survey responses
during the development of the proposed NESHAP, inorganic HAP, including
chromium, cobalt, hydrogen chloride, lead, manganese compounds and
nickel, are components of some coatings, dyes, and finishes used by
this source category. Inorganic HAP are not likely to be emitted
because of the application techniques used.
D. What Is the Affected Source?
We define an affected source as a stationary source, a group of
stationary sources, or part of a stationary source to which a specific
emission standard applies. The proposed standards define the affected
source for each subcategory as the collection of all equipment
associated with the coating and printing, the slashing, or the dyeing
and finishing performed on a textile substrate. For the purpose of
defining the affected source, the textile substrate includes staple
fibers and filaments suitable for conversion to or use as yarns, or for
the preparation of woven, knit, or nonwoven fabrics; yarns made from
natural or manufactured fibers; fabrics and other manufactured products
made from staple fibers and filaments and from yarn; and garments and
other articles fabricated from fibers, yarns, or fabrics. Also for each
subcategory, the specific regulated materials are defined. Regulated
materials are the HAP-containing materials that are the source of HAP
emissions limited by the requirements of the proposed NESHAP.
The affected source for the coating and printing subcategory
includes: all web coating and printing equipment used to apply cleaning
materials to a substrate to prepare it for coating or printing material
application, to apply coating or printing materials to a substrate and
to dry or cure the coating or printing materials after application by
exposure to heat or radiation (coating or printing material drying or
curing), or to clean coating/printing operation equipment; all storage
containers and mixing vessels in which regulated materials are stored
or mixed; all manual and automated equipment and containers used for
conveying regulated materials; all storage containers and all manual
and automated equipment and containers used for conveying waste
materials generated by a coating or printing operation; and all manual
and automated equipment, structures, and devices used to convey, treat,
or dispose of wastewater streams or residuals. Coating or printing
material drying or curing at ambient conditions is not drying or curing
for the purpose of the proposed standards. The regulated materials for
the coating and printing subcategory are the coating, printing,
thinning and cleaning materials used in the affected source.
The affected source for the slashing subcategory includes: all
slashing equipment used to apply and dry size on warp yarn; all storage
containers and mixing vessels in which regulated materials are stored
or mixed; all manual and automated equipment and containers used for
conveying regulated materials; all storage containers and all manual
and automated equipment and containers used for conveying waste
materials generated by a slashing operation; and all manual and
automated equipment, structures, and devices used to convey, treat, or
dispose of wastewater streams or residuals. The regulated materials for
the slashing subcategory are the slashing materials used in the
affected source.
The affected source for the dyeing and finishing subcategory
includes: all dyeing and finishing equipment used to apply dyeing or
finishing materials, to fix dyeing materials to the substrate, to rinse
the textile substrate, to dry or cure the dyeing or finishing
materials, or to clean dyeing/finishing operation equipment; all
storage containers and mixing vessels in which regulated materials are
stored or mixed; all manual and automated equipment and containers used
for conveying regulated materials; all storage containers and all
manual and automated equipment and containers used for conveying waste
materials generated by a dyeing or finishing operation; and all manual
and automated equipment, structures, and devices used to convey, treat,
or dispose of wastewater streams or residuals. The regulated materials
for the dyeing and finishing subcategory are the dyeing, finishing, and
cleaning materials used in the affected source.
E. What Are the Emission Limits, Operating Limits, and Other Standards?
We are proposing standards that would limit organic HAP emissions
from coating, printing, slashing, dyeing, and finishing operations. The
proposed standards include emission limits, operating limits, and work
practice standards. Emission limits are being proposed for the coating
and printing, slashing, and dyeing and finishing subcategories.
Operating limits and work practice standards are being proposed for the
coating and printing subcategory.
Emission limits. In the coating and printing subcategory, we are
proposing to limit organic HAP emissions to the atmosphere from each
new and reconstructed affected source to one of the following three
specified levels: (1) At least a 98 percent organic HAP OCE (OCE
limit); (2) no more than 0.08 kilograms (kg) organic HAP/kg of coating
solids used (0.08 pound (lb) organic HAP/lb of coating solids used)
during each monthly compliance period (emission rate limit); or (3) if
you are using an oxidizer to control organic HAP emissions, operate the
oxidizer such that an outlet organic HAP concentration of no greater
than 20 parts per million by volume (ppmv) on a dry basis is achieved
and the efficiency of the capture system is 100 percent (outlet
concentration limit). The proposed HAP emission limits for each
existing affected source are: (1) To achieve at least a 97 percent OCE
limit; (2) an emission rate limit of no more than 0.12 kg organic HAP/
kg of coating solids used (0.12 lb organic HAP/lb of coating solids
used) in each monthly compliance period; or (3) if you are using an
oxidizer to control organic HAP emissions, operate the oxidizer to
achieve the outlet concentration limit of no greater than 20 ppmv on a
dry basis and the efficiency of the capture system is 100 percent.
You may choose from several compliance options in the proposed rule
to achieve the coating and printing emission limits. You could comply
through a pollution prevention approach by applying regulated materials
that meet the emission rate
[[Page 46033]]
limits, either individually (compliant material option) or collectively
(emission rate without add-on controls option), during each monthly
compliance period. Second, you could use a capture system and add-on
control device to meet either the applicable organic HAP OCE limit or
emission rate limit. Third, you could use a 100 percent efficient
capture system and an oxidizer that reduces organic HAP emissions to no
more than 20 ppmv.
In the slashing subcategory, we are proposing to require each new,
reconstructed and existing affected source to emit no organic HAP. This
is not an absolute zero HAP limit since the compliance procedures
specify that to determine organic HAP emissions, you would count only
organic HAP present in the materials you use at 0.1 percent by mass or
more for OSHA-defined carcinogens as specified in 29 CFR
1910.1200(d)(4) and at 1 percent or more for other organic HAP
compounds. To comply with the slashing organic HAP emission limits, you
must apply only materials that individually meet the standard during
each monthly compliance period.
In the dyeing and finishing subcategory, we are proposing to limit
organic HAP emissions from each new, reconstructed and existing
affected source that conducts dyeing operations only or both dyeing and
finishing operations to no more than 0.016 kg organic HAP per kg of
dyeing material used (0.016 lb organic HAP per lb of dyeing material
used) for each monthly compliance period. You could comply with the
dyeing and finishing organic HAP emission rate by applying materials
that meet the emission rate, either individually or collectively,
during each monthly compliance period. Each new, reconstructed and
existing affected source that conducts only finishing operations is
required to emit no organic HAP. This is not an absolute zero HAP limit
since the compliance procedures specify that to determine organic HAP
emissions, you would count only organic HAP that are present in the
materials you use at 0.1 percent by mass or more for Occupational
Safety and Health Administration (OSHA)-defined carcinogens as
specified in 29 CFR 1910.1200(d)(4) and at 1 percent or more for other
organic HAP compounds.
Operating limits. If you reduce emissions from coating or printing
operations by using a capture system and add-on control device (other
than a solvent recovery system for which you conduct a liquid-liquid
material balance), the proposed operating limits would apply to you.
These limits are site-specific parameter limits that you determine
during the initial performance test of the system. For capture systems
that are not permanent total enclosures (PTE), you would establish
average volumetric flow rates or duct static pressure limits for each
capture device (or enclosure) in each capture system. For capture
systems that are PTE, you would establish limits on average facial
velocity or pressure drop across openings in the enclosure.
For thermal oxidizers, you would monitor the combustion
temperature. For catalytic oxidizers, you would either monitor the
temperature immediately before and after the catalyst bed, or you would
monitor the temperature before the catalyst bed and prepare and
implement an inspection and maintenance plan that includes periodic
catalyst activity checks. For carbon adsorbers for which you do not
conduct a liquid-liquid material balance, you would monitor the carbon
bed temperature and the amount of steam or nitrogen used to desorb the
bed. For condensers, you would monitor the outlet gas temperature from
the condenser. For concentrators, you would monitor the temperature in
the desorption gas stream and the pressure drop across the zeolite
wheel or rotary carbon bed.
The site-specific parameter limits that you establish must reflect
operation of the capture system and add-on control devices during a
performance test that demonstrates achievement of the emission limits
during representative operating conditions.
Work practice standards. If you use an emission capture system and
add-on control device for compliance, you would be required to develop
and implement a work practice plan to minimize organic HAP emissions
from mixing operations, storage tanks and other containers, and
handling operations for coating, printing, thinning, cleaning, and
waste materials.
Operations during startup, shutdown, or malfunction. If you use a
capture system and add-on control device for compliance, you would be
required to develop and operate according to a startup, shutdown, and
malfunction plan (SSMP) during periods of startup, shutdown, or
malfunction of the capture system and add-on control device.
General Provisions. The General Provisions (40 CFR part 63, subpart
A) would also apply to you as indicated in the proposed rule. The
General Provisions codify certain procedures and criteria for all 40
CFR part 63 NESHAP. The General Provisions contain administrative
procedures, preconstruction review procedures for new sources, and
procedures for conducting compliance-related activities such as
notifications, reporting and recordkeeping, performance testing, and
monitoring. The proposed rule refers to individual sections of the
General Provisions to emphasize key sections that are relevant.
However, unless specifically overridden in the proposed rule, all of
the applicable General Provisions requirements would apply to you.
F. What Are the Testing and Initial Compliance Requirements?
Compliance dates. Existing affected sources would have to be in
compliance with the final standards no later than [DATE 3 YEARS AFTER
PUBLICATION OF THE FINAL RULE IN THE FEDERAL REGISTER]. New and
reconstructed affected sources would have to be in compliance upon
startup of the affected source or by the [DATE OF PUBLICATION OF THE
FINAL RULE IN THE FEDERAL REGISTER], whichever is later. The effective
date is the date on which the final rule is published in the Federal
Register.
The proposed initial compliance period begins on the compliance
date and ends on the last day of the first full month following the
compliance date; except for new and reconstructed sources required to
conduct performance tests, the initial compliance period ends on the
last day of the first full month following the performance test if the
performance test is conducted later than the compliance date (the
proposed rule allows the test to be conducted up to 180 days later).
Being ``in compliance'' means that the owner or operator of the
affected source meets the requirements to achieve the emission
limitations during the initial compliance period. At the end of the
initial compliance period, the owner or operator would use the data and
records generated to determine whether or not the affected source is in
compliance with the organic HAP emission limit and other applicable
requirements for that period. If the affected source does not meet the
emission limit and other applicable requirements, it is out of
compliance for the entire initial compliance period.
Emission limits. With the exception of the slashing emission limit,
there are several proposed options for complying with the proposed
emission limits, and the testing and initial compliance requirements
vary accordingly. You would be able to use different compliance options
for different coating, printing, dyeing, and finishing operations in
the affected source for
[[Page 46034]]
each subcategory and also for the same operation at different times.
Compliance based on materials used in the affected source. If you
demonstrate compliance with the proposed coating and printing emission
limits based on the materials used, you would determine the mass of
organic HAP and the mass fraction of solids in all materials used
during the month of the initial compliance period. You would be
required to demonstrate either that the organic HAP content of each
coating and printing material meets the applicable emission limit and
that you use no organic HAP-containing thinning or cleaning materials
(compliant material option); or that the total mass of organic HAP in
all coating, printing, thinning, and cleaning materials used divided by
the total mass of solids in coating and printing materials used meets
the applicable emission limit (emission rate without add-on controls
option).
The compliant material option is a pollution prevention option that
allows you to easily demonstrate compliance by using low-HAP or non-HAP
coating and printing materials. If you use coating and printing
materials that, based on their organic HAP content, individually meet
the kg (lb) organic HAP emitted per kg (lb) solids used levels in the
applicable emission limits and you use non-HAP thinners and other
additives and cleaning materials, this compliance option is available
to you. For this option, we have minimized recordkeeping and reporting
requirements. You can demonstrate compliance by using readily available
purchase records containing manufacturer's formulation data to
determine the organic HAP content of each coating, printing, or other
material and the amount of each material used. You would not need to
perform any detailed emission rate calculations.
To demonstrate compliance with the compliant material option, you
would demonstrate that the organic HAP content of each coating and
printing material meets the applicable emission limit in Table 1 to the
proposed subpart, and that you used no organic HAP-containing thinning
or cleaning materials. For example, if you are using the compliant
materials option for your existing source, you would demonstrate that:
(1) Each coating and printing material used has an organic HAP content
no greater than 0.12 kg (0.12 lb) organic HAP per kg (lb) solids used,
(2) and that you used no organic HAP-containing thinning or cleaning
materials. Note that ``no organic HAP'' is not intended to mean
absolute zero. Materials that contain ``no organic HAP'' should be
interpreted to mean materials that contain organic HAP levels below the
levels specified in Sec. 63.4341(e) of the proposed rule, which are
typical reporting levels. These typical reporting levels only count
organic HAP that are present at 0.1 percent or more by mass for OSHA-
defined carcinogens and at 1.0 percent or more by mass for other
compounds.
To determine the mass fraction of organic HAP in coating, printing,
thinning, and cleaning materials and the mass fraction of solids in
coating and printing materials, you could rely on manufacturer's
formulation data. You would not be required to perform tests or
analysis of the material if formulation data are available.
Alternatively, you could use results from the test methods listed
below. You may also use alternative test methods provided you get EPA
approval in accordance with the NESHAP General Provisions, 40 CFR
63.7(f). However, if there is any inconsistency between the test method
results (either EPA's or an approved alternative) and manufacturer's
data, the test method results would prevail for compliance and
enforcement purposes.
For mass fraction of organic HAP, you would use Method 311
of 40 CFR part 63, appendix A;
The proposed rule would allow you to use nonaqueous
volatile matter as a surrogate for organic HAP, which would include all
organic HAP plus all other organic compounds, and excluding water. If
you choose this option, you would use Method 24 of 40 CFR part 60,
appendix A; and
For mass fraction of solids, you would use Method 24 of 40
CFR part 60, appendix A.
The emission rate without add-on controls option is a pollution
prevention option where you can demonstrate compliance based on the
organic HAP contained in the mix of coating, printing, thinning, and
cleaning materials you use. This option allows you the flexibility to
use some individual coating or printing materials that do not
individually meet the emission limit if you use other low-HAP or non-
HAP coating or printing materials such that overall emissions from the
affected source during the compliance period meet the emission limit.
To demonstrate initial compliance with the emission rate limit
without add-on controls option, you would be required to:
Determine the quantity of each coating, printing,
thinning, and cleaning material you used.
Calculate the mass of organic HAP in each coating,
printing, thinning, and cleaning material using the same types of data
and methods previously described for the compliant material option.
Determine the mass fraction of solids for each coating and
printing material you used using the same types of data or methods
described for the compliant material option.
Calculate the total mass of organic HAP in all materials
used and total mass of solids for all coating and printing materials
used. You may subtract from the total mass of organic HAP the amount
contained in waste materials you send to a hazardous waste treatment,
storage, and disposal facility regulated under 40 CFR part 262, 264,
265, or 266.
Calculate the ratio of the total mass of organic HAP to
the total mass of solids for the materials used.
Record the calculations and results and include them in
your Notification of Compliance Status.
Note that if you choose to use this option for a particular
coating/printing operation or group of operations rather than for an
entire affected source, you would calculate the organic HAP emission
rate using just the materials used in that operation or group. You
would need to separately demonstrate compliance for all other
operations in the affected source.
To demonstrate compliance with the proposed slashing emission
limits, you must use the compliant material option and demonstrate that
each slashing material used during the initial compliance period
contains no organic HAP. As was noted regarding thinning or cleaning
materials used in coating/printing operations, ``no organic HAP'' is
not intended to mean absolute zero. Materials that contain ``no organic
HAP'' should be interpreted to mean materials that contain organic HAP
levels below the levels specified in Sec. 63.4341(e) of the proposed
rule, which are typical reporting levels.
To demonstrate compliance with the proposed dyeing and finishing
emission limits, you would be required to demonstrate either that the
organic HAP content of each dyeing, finishing and cleaning material
meets the applicable emission limit (compliant material option) or that
the total mass of organic HAP in all dyeing, finishing and cleaning
materials used divided by the total mass of dyeing, finishing and
cleaning materials used meets the applicable emission limit (emission
rate without add-on controls option).
As previously described for coating/printing operations, the
compliant material option is a pollution prevention option that allows
you to
[[Page 46035]]
easily demonstrate compliance by using low-HAP or non-HAP dyeing,
finishing and cleaning materials. To demonstrate compliance with the
compliant material option, you would demonstrate that the organic HAP
content of each dyeing, finishing, and cleaning material meets the
applicable emission limit in Table 1 to the proposed subpart. To
determine the mass of organic HAP in dyeing, finishing and cleaning
materials, you may rely on manufacturer's formulation data. You would
not be required to perform tests or analysis of the material if
formulation data are available. Alternatively, you could use results
from the test methods listed below. You may also use alternative test
methods provided you get EPA approval in accordance with the NESHAP
General Provisions, 40 CFR 63.7(f). However, if there is any
inconsistency between the test method results (either EPA's or an
approved alternative) and manufacturer's data, the test method results
would prevail for compliance and enforcement purposes.
For mass fraction of organic HAP, you would use Method 311
of 40 CFR part 63, appendix A;
The proposed rule would allow you to use nonaqueous
volatile matter as a surrogate for organic HAP, which would include all
organic HAP plus all other organic compounds, and excluding water. If
you choose this option, you would use Method 24 of 40 CFR part 60,
appendix A.
Again as previously described for coating/printing operations, the
emission rate without add-on controls option is a pollution prevention
option where you can demonstrate compliance based on the organic HAP
contained in the mix of dyeing, finishing, and cleaning materials you
use. This option allows you more flexibility that the compliant
material option, but requires the calculation of the emission rate each
month. To demonstrate initial compliance with the emission rate without
add-on controls option, you would be required to:
Determine the mass of each dyeing, finishing and cleaning
material you used.
Calculate the mass of organic HAP in each dyeing,
finishing and cleaning material.
Calculate the total mass of organic HAP in all materials
and the total mass of all materials used for the compliance period. You
may subtract from the total mass of organic HAP the amount contained in
waste materials you send to a hazardous waste treatment, storage, and
disposal facility regulated under 40 CFR part 262, 264, 265, or 266.
Calculate the ratio of the total mass of organic HAP in
the materials used to the total mass of materials used.
Record the calculations and results and include them in
your Notification of Compliance Status.
Note that if you choose to use this option for a particular dyeing/
finishing operation or group of operations rather than for an entire
affected source, you would calculate the organic HAP emission rate
using just the materials used in that operation or group. You would
need to separately demonstrate compliance for all other operations in
the affected source.
Compliance based on using a capture system and add-on control
device for coating and printing operations. If you use a capture system
and add-on control device on a coating/printing operation, other than a
solvent recovery system for which you conduct a liquid-liquid material
balance, you would determine the capture and control efficiencies of
the equipment or the oxidizer outlet organic HAP concentration. For the
organic HAP emission rate limit, you also would determine the mass
fraction of organic HAP and the mass fraction of solids in all
materials used during the month of the initial compliance period. You
would be required to demonstrate either that the organic HAP OCE is
greater than or equal to the applicable organic HAP OCE limit, that the
oxidizer outlet organic HAP concentration is no greater than 20 ppmv on
a dry basis and the efficiency of the capture system is 100 percent, or
that the capture and control system reduces organic HAP emissions to a
level no greater than the applicable emission rate limit.
If you use a solvent recovery system for which you conduct a
liquid-liquid material balance, you would be required to demonstrate
either that the organic HAP OCE determined by material balance during
the month of the initial compliance period is greater than or equal to
the applicable organic HAP OCE limit or that the solvent recovery
system reduces organic HAP emissions to a level no greater than the
applicable emission rate limit.
The proposed testing and initial compliance requirements associated
with determining the OCE of the capture system and add-on control
device are summarized in the following paragraphs.
If you use a capture system and add-on control device, other than a
solvent recovery system for which you conduct material balances, you
would be required to conduct an initial performance test to determine
the capture and control efficiencies of the equipment (or the capture
efficiency of the capture system and the oxidizer outlet organic HAP
concentration) and to establish operating limits to be achieved on a
continuous basis. The performance test would have to be completed no
later than the compliance date for existing sources and 180 days after
the compliance date for new and reconstructed sources. If you are
demonstrating compliance with the applicable emission rate limit with
add-on controls, you would need to schedule the performance test in
time to obtain the results for use in calculating your emission rate
for the month of the initial compliance period.
You would determine both the efficiency of the capture system and
either the organic HAP emission reduction efficiency of the add-on
control device or the outlet organic HAP concentration of the oxidizer.
To determine the capture efficiency, you would either verify the
presence of a PTE using EPA Method 204 of 40 CFR part 51, appendix M
(and all materials must be applied and dried or cured within the
enclosure); or use one of three protocols in proposed Sec. 63.4365 to
measure capture efficiency. If you have a PTE and all regulated
materials are applied and dried or cured within the enclosure and you
route all exhaust gases from the enclosure to an add-on control device,
then you would assume 100 percent capture. To demonstrate compliance
with the oxidizer outlet organic HAP concentration limit, 100 percent
capture is required.
To determine the organic HAP emission reduction efficiency of the
add-on control device, you would conduct measurements of the inlet and
outlet gas streams. Only the outlet gas stream would be measured to
determine outlet concentration. The performance test would consist of
three runs, each run lasting 1 hour, using the following EPA Methods in
40 CFR part 60, appendix A:
Method 1 or 1A for selection of the sampling sites.
Method 2, 2A, 2C, 2D, 2F, or 2G to determine the gas
volumetric flow rate.
Method 3, 3A, or 3B for gas analysis to determine dry
molecular weight. You may also use as an alternative to Method 3B, the
manual method for measuring the oxygen, carbon dioxide, and carbon
monoxide content of exhaust gas in ANSI/ASME PTC 19.10-1981.
Method 4 to determine stack moisture.
Method 25 or 25A to determine organic volatile matter
concentration. You would use Method 25A to demonstrate compliance with
the oxidizer outlet organic HAP
[[Page 46036]]
concentration limit because the limit is less than 50 ppmw.
Alternatively, any other test method or data that have been validated
according to the applicable procedures in Method 301 of 40 CFR part 63,
appendix A, and approved by the Administrator, could be used.
If you use a solvent recovery system, you could determine the OCE
using a liquid-liquid material balance instead of conducting an initial
performance test. If you use the material balance alternative, you
would be required to measure the amount of all materials used during
the month of the initial compliance period and determine the total
volatile matter contained in these materials. You would also measure
the amount of volatile matter recovered by the solvent recovery system
during the compliance period. Then you would compare the amount
recovered to the amount used to determine the OCE. You would record the
calculations and results and include them in your Notification of
Compliance Status.
Additional proposed testing and initial compliance requirements
associated with demonstrating compliance using the emission rate with
add-on controls option are as follows:
Determine the mass fraction of organic HAP in each
coating, printing, thinning, and cleaning material used and the mass
fraction of solids in coating and printing materials used during the
month of the initial compliance period, as described previously in
``Compliance based on materials used in the affected source.''
Calculate the total mass of organic HAP in all materials
and total mass of solids for all coating and printing materials. You
may subtract from the total mass of organic HAP the amount contained in
waste materials you send to a hazardous waste treatment, storage, and
disposal facility regulated under 40 CFR part 262, 264, 265, or 266.
Calculate the organic HAP emission reductions from the
controlled coating or printing operations using the capture and control
efficiencies determined during the performance test or the materials
balance for the month and the total mass of organic HAP in materials
used in controlled coating and printing operations.
Calculate the ratio of the total mass of HAP emissions to
the total mass of solids for the materials used during the month of the
initial compliance period.
Record the calculations and results and include them in
your Notification of Compliance Status.
Develop and implement a work practice plan to minimize
emissions from storage, mixing, and handling of organic HAP-containing
materials.
Operating limits. As mentioned above, you would establish operating
limits as part of the initial performance test of a capture system and
add-on control device, other than a solvent recovery system for which
you conduct liquid-liquid material balances. The operating limits are
the minimum or maximum (as applicable) values achieved for capture
systems and add-on control devices during the performance test,
conducted under representative conditions, that demonstrated compliance
with the emission limits.
The proposed rule specifies the parameters to monitor for the types
of emission control systems commonly used in the industry. You would be
required to install, calibrate, maintain, and continuously operate all
monitoring equipment according to the manufacturer's specifications and
ensure that the continuous parameter monitoring systems (CPMS) meet the
requirements in Sec. 63.4374 of the proposed rule. If you use add-on
control devices other than those identified in the proposed rule, you
would submit the operating parameters to be monitored to the
Administrator for approval. The authority to approve the parameters to
be monitored is retained by EPA and is not delegated to States.
If you use a thermal or catalytic oxidizer, you would continuously
monitor the appropriate temperature and record it at least every 15
minutes. For thermal oxidizers, the temperature monitor is placed in
the firebox or in the duct immediately downstream of the firebox before
any substantial heat exchange occurs. The operating limit would be the
average temperature measured during the performance test, and for each
consecutive 3-hour period the average temperature would have to be at
or above this limit. For catalytic oxidizers, temperature monitors are
placed immediately before and after the catalyst bed. The operating
limits would be the average temperature just before the catalyst bed
and the average temperature difference across the catalyst bed during
the performance test. For each 3-hour period, the average temperature
and the average temperature difference would have to be at or above
these limits. Alternatively, you would be allowed to meet only the
temperature limit before the catalyst bed if you develop and implement
an inspection and maintenance plan that includes periodic catalyst
activity checks.
If you use a carbon adsorber and do not conduct liquid-liquid
material balances to demonstrate compliance, you would monitor the
carbon bed temperature after each regeneration and the total amount of
steam or nitrogen used to desorb the bed for each regeneration. The
operating limits would be the carbon bed temperature (not to be
exceeded) and the amount of steam or nitrogen used for desorption (to
be met as a minimum).
If you use a condenser and do not conduct liquid-liquid material
balances to demonstrate compliance, you would monitor the outlet gas
temperature to ensure that the air stream is being cooled to a low
enough temperature. The operating limit would be the average condenser
outlet gas temperature measured during the performance test, and for
each consecutive 3-hour period the average temperature would have to be
at or below this limit.
If you use a concentrator, you would monitor the desorption
concentrate stream gas temperature and the pressure drop of the dilute
stream across the concentrator. These values would be recorded at least
once every 15 minutes. The operating limits would be the average
temperature (to be met as a minimum) and the average pressure drop (not
to be exceeded) measured during the performance test.
For each capture system that is not a PTE, you would establish
operating limits for gas volumetric flow rate or duct static pressure
for each enclosure or capture device. The operating limit would be the
average volumetric flow rate or duct static pressure during the
performance test to be met as a minimum. For each capture system that
is a PTE, the operating limit would require the average facial velocity
of air through all natural draft openings to be at least 200 feet per
minute or the pressure drop across the enclosure to be at least 0.007
inch water.
Work practices. If you use a capture system and add-on control
device for compliance, you would be required to develop and implement
on an ongoing basis a work practice plan for minimizing organic HAP
emissions to the atmosphere from storage, mixing, material handling,
and waste handling operations. This plan would include a description of
all steps taken to minimize emissions from these sources (e.g., using
closed storage containers, practices to minimize emissions during
filling and transfer of contents from containers, using spill
minimization techniques, placing solvent-laden cloths in closed
containers immediately after use, etc.). You would have to make the
plan available for inspection if the Administrator requests to see it.
Operations during startup, shutdown, or malfunction. If you use a
capture
[[Page 46037]]
system and add-on control device for compliance, you would be required
to develop and operate according to a SSMP during periods of startup,
shutdown, or malfunction of the capture system and add-on control
device.
G. What Are the Continuous Compliance Provisions?
Emission limits. If you demonstrate compliance with the proposed
emission limits for slashing based on the materials used (compliant
material option), you would demonstrate continuous compliance if, for
each monthly compliance period, the organic HAP content of each
slashing material used meets the emission limits. You would use
manufacturer's data to demonstrate compliance each month as you did for
the initial compliance period.
If you demonstrate compliance with the proposed emission limits for
coating and printing based on the materials used, you would demonstrate
continuous compliance if, for each monthly compliance period, either
you use only coating and printing materials that meet the applicable
emission limit and only non-HAP thinning and cleaning materials
(compliant material option); or that the ratio of total mass of organic
HAP to total mass of solids in coating and printing materials used is
less than or equal to the emission limits (emission rate without add-on
controls option). You would follow the same procedures for calculating
the organic HAP to coating and printing solids ratio that you used for
the initial compliance period.
If you demonstrate compliance with the proposed emission limits for
dyeing and finishing based on the materials used, you would demonstrate
continuous compliance if, for each monthly compliance period, either
the organic HAP content of each dyeing, finishing and cleaning material
meets the applicable emission limit (compliant material option) or the
total mass of organic HAP in all dyeing, finishing and cleaning
materials used divided by the total mass of dyeing, finishing and
cleaning materials used meets the applicable emission limit (emission
rate without add-on controls option). You would follow the same
procedures for determining the mass of organic HAP in all materials
used during the month that you used for the initial compliance period.
For each coating or printing operation on which you use a capture
system and add-on control device, other than solvent recovery for which
you conduct a liquid-liquid material balance, the continuous parameter
monitoring results for each month would affect your compliance
determination. If the monitoring results indicate no deviations from
the operating limits and there were no bypasses of the add-on control
device, you would assume the capture system and add-on control device
are achieving the same emission reduction as they did during the
performance test in which the operating limits were established. If you
are demonstrating compliance with either the organic HAP OCE option or
the emission rate with add-on controls option, you would then apply the
OCE to the total mass of organic HAP in materials used in controlled
coating or printing operations to determine the monthly mass of organic
HAP emissions from those operations. If there were any deviations from
the operating limits during the month or any bypasses of the add-on
control device, you would account for them in the calculation of the
applicable emission rate by assuming the capture system and add-on
control device were achieving zero emission reduction during the
periods of deviation.
For each coating and printing operation on which you use a solvent
recovery system and conduct a liquid-liquid material balance each
month, you would use the liquid-liquid material balance to determine
the emission rate. You would be required to measure the amount of all
materials used during each month and determine the volatile matter
content of these materials. You would also measure the amount of
volatile matter recovered by the solvent recovery system during the
month and calculate the weight percent of organic HAP used that was
emitted to determine compliance with the organic HAP OCE option. If you
are complying with the emission rate with add-on controls option, you
would apply the OCE to the total mass of organic HAP in the materials
used to determine total organic HAP emissions as input to the
compliance demonstration.
Operating limits. If you use an emission capture system and add-on
control device, the proposed rule would require you to achieve on a
continuous basis the operating limits you establish during the
performance test. If the continuous monitoring shows that the capture
system and add-on control device are operating outside the range of
values established during the performance test, you have deviated from
the established operating limits.
If you operate a capture system and add-on control device with
bypass lines that could allow emissions to bypass the add-on control
device, you would have to demonstrate that organic HAP emissions
collected by the capture system are routed to the add-on control device
by monitoring for potential bypass of the add-on control device. You
may choose from the following four monitoring procedures:
Flow control position indicator to provide a record of
whether the exhaust stream is directed to the add-on control device;
Car-seal or lock-and-key valve closures to secure the
bypass line valve in the closed position when the add-on control device
is operating;
Valve closure continuous monitoring to ensure any bypass
line valve or damper is closed when the add-on control device is
operating; or
Automatic shutdown system to stop the coating or printing
operation when flow is diverted from the add-on control device.
A deviation would occur for any period of time the bypass
monitoring procedures indicate that emissions are not routed to the
add-on control device.
Work practices. If you use an emission capture system and add-on
control device for compliance, you would be required to implement on an
ongoing basis the work practice plan you developed during the initial
compliance period. If you did not develop a plan for reducing organic
HAP emissions or you do not implement the plan, this would be a
deviation from the work practice standard.
Operations during startup, shutdown, and malfunction. If you use a
capture system and add-on control device for compliance, you would be
required to develop and operate according to a SSMP during periods of
startup, shutdown, and malfunction of the capture system and add-on
control device.
H. What Are the Notification, Recordkeeping, and Reporting
Requirements?
You would be required to comply with the applicable requirements in
the NESHAP General Provisions, subpart A of 40 CFR part 63, as
described in the proposed rule. The General Provisions notification
requirements include: initial notifications, notification of
performance test if you are complying using a capture system and add-on
control device, notification of compliance status, and additional
notifications required for affected sources with continuous monitoring
systems. The General Provisions also require certain records and
periodic reports.
Initial notifications. If you own or operate an existing affected
source, you would be required to send a notification
[[Page 46038]]
to the EPA Regional Office in the region where your affected source is
located and to your State agency no later than [DATE 1 YEAR FROM DATE
OF PUBLICATION OF THE FINAL RULE IN THE FEDERAL REGISTER]. For new and
reconstructed sources, you would send the notification within 120 days
after the date of initial startup or [DATE 120 DAYS FROM DATE OF
PUBLICATION OF THE FINAL RULE IN THE FEDERAL REGISTER], whichever is
later. The report notifies us and your State agency that you have an
existing affected source that is subject to the proposed standards, or
that you have constructed a new affected source. Thus, it allows you
and the permitting authority to plan for compliance activities. You
would also need to send a notification of planned construction or
reconstruction of a source that would be subject to the proposed rule
and apply for approval to construct or reconstruct.
Notification of performance test. If you demonstrate compliance by
using a capture system and add-on control device for which you do not
conduct a liquid-liquid material balance, you would conduct a
performance test. The performance test would be required no later than
the compliance date for an existing affected source. For a new or
reconstructed affected source, the performance test would be required
no later than 180 days after initial startup or [180 DAYS FROM DATE OF
PUBLICATION OF THE FINAL RULE IN THE Federal Register], whichever is
later. You must notify us (or the delegated State or local agency) at
least 60 calendar days before the performance test is scheduled to
begin and submit a report of the performance test results no later than
60 days after the test.
Notification of compliance status. You would send us a Notification
of Compliance Status within 30 days after the end of the initial
compliance period. In the notification, you would certify whether each
affected source has complied with the proposed standards, identify the
option(s) you used to demonstrate initial compliance, summarize the
data and calculations supporting the compliance demonstration, and
provide information on any deviations from the emission limits,
operating limits, or other requirements.
If you elect to comply by using a capture system and add-on control
device for which you conduct performance tests, you must provide the
results of the tests. Your notification would also include the measured
range of each monitored parameter, the operating limits established
during the performance test, and information showing whether the source
has complied with its operating limits during the initial compliance
period.
Recordkeeping requirements. You would be required to keep records
of reported information and all other information necessary to document
compliance with the proposed rule for 5 years. As required under the
General Provisions, records for the 2 most recent years must be kept
on-site; the other 3 years' records may be kept off-site. Records
pertaining to the design and operation of the emission control and
monitoring equipment must be kept for the life of the equipment.
You would need to keep all documentation supporting initial
notifications and notifications of compliance status.
If your affected source is complying with the slashing emission
limits, you would need to keep records of the organic HAP content of
each slashing material as purchased.
Depending on the compliance option that you choose for your
affected source complying with the dyeing and finishing or coating and
printing emission limits, you would need to keep records of the
following:
Organic HAP content, volatile matter content, coating and
printing materials solids content, and quantity of the dyeing,
finishing, coating, printing, thinning, and cleaning materials used
during each compliance period.
For the emission rate (with or without add-on controls)
compliance options, calculations of your emission rate for each
compliance period.
If your affected source is in the coating and printing subcategory
and you demonstrate compliance by using a capture system and add-on
control device, you would also need to keep records of the following:
All required measurements, calculations, and supporting
documentation needed to demonstrate compliance with the standards.
All results of performance tests and parameter monitoring.
All information necessary to demonstrate conformance with
your plan for minimizing emissions from mixing, storage, and waste
handling operations.
All information necessary to demonstrate conformance with
the affected source's SSMP when the plan procedures are followed.
The occurrence and duration of each startup, shutdown, or
malfunction of the emission capture system and add-on control device.
Actions taken during startup, shutdown, and malfunction
that are different from the procedures specified in the affected
source's SSMP.
Each period during which a CPMS is malfunctioning or
inoperative (including out-of-control periods).
The proposed rule would require you to collect and keep records
according to certain minimum data requirements for the CPMS. Failure to
collect and keep the specified minimum data would be a deviation that
is separate from any emission limits, operating limits, or work
practice standards.
Deviations, as determined from these records, would need to be
recorded and also reported. A deviation is any instance when any
requirement or obligation established by the proposed rule including,
but not limited to, the emission limits, operating limits, and work
practice standards, is not met.
If you use a capture system and add-on control device to reduce
organic HAP emissions, you would have to make your SSMP available for
inspection if the Administrator requests to see it. The plan would stay
in your records for the life of the affected source or until the source
is no longer subject to the proposed standards. If you revise the plan,
you would need to keep the previous superseded versions on record for 5
years following the revision.
Periodic reports. Each reporting year is divided into two
semiannual reporting periods. If no deviations occur during a
semiannual reporting period, you would submit a semiannual report
stating that the affected source has been in continuous compliance. If
deviations occur, you would include them in the report as follows:
Report each deviation from the emission limit.
Report each deviation from the work practice standards if
you use an emission capture system and add-on control device.
If you use an emission capture system and add-on control
device other than a solvent recovery system for which you conduct
liquid-liquid material balances, report each deviation from an
operating limit and each time a bypass line diverts emissions from the
add-on control device to the atmosphere.
Report other specific information on the periods of time
the deviations occurred.
You would also have to include in each semiannual report an
identification of the compliance option(s) you used for each affected
source and any time periods when you changed to another compliance
option.
Other reports. You would be required to submit reports for periods
of startup, shutdown, or malfunction of the capture
[[Page 46039]]
system and add-on control device. If the procedures you follow during
any startup, shutdown, or malfunction are inconsistent with your SSMP,
you would report those procedures with your semiannual reports in
addition to immediate reports required by 40 CFR 63.10(d)(5)(ii).
Electronic reporting option. Comments are invited on the option of
voluntary electronic reporting for all reporting requirements in the
proposed rule. The option would allow the use of the Internet to meet
the reporting requirements of the proposed rule. You would be allowed
to choose the option to submit all reports electronically in lieu of
filing written reports. The electronic records submittals would need to
include all the information that otherwise would be submitted in
written reports. The electronic submittals would be via electronic data
interchange and would use Data Exchange Templates (DET). The DET or
electronic forms will be used to ``tag'' data elements, which will
allow reporting of the information to EPA. You would submit the
electronic forms through EPA's Central Data Exchange (CDX). We would
supply the required data elements, and you would be responsible for
submitting the data appropriately ``tagged.'' If the rule were
delegated to State, local or tribal agencies for implementation and
enforcement, EPA would coordinate with the delegated agencies to
provide them with either the electronic information or a hard copy of
the required report.
Under this proposed electronic reporting option, it would be
necessary to establish: (1) That an electronic document was sent (or
not sent); (2) when the document was sent; (3) by whom the document was
sent, and including both the individual who sent it and the identity of
the entity the individual is authorized to represent; (4) when the
document was received; (5) that the document was not altered from the
time it was sent to the time it was received; and (6) the contents of
the document sent.
Specifically, we request comment on the concept of electronic
reporting, advantages to the regulated community by reducing reporting
burdens; cost or cost savings; advantages or disadvantages to State/
local/tribal agencies; and difficulties to be overcome in the
implementation of electronic reporting.
III. Rationale for Selecting the Proposed Standards
A. How did We Select The Source Category and Subcategories?
Printing, coating, and dyeing of fabrics (changed by today's action
to printing, coating, and dyeing of fabrics and other textiles) is a
source category that is on the list of source categories to be
regulated because it contains major sources which emit or have the
potential to emit at least 10 tons of any one HAP or at least 25 tons
of any combination of HAP annually. The proposed rule would control HAP
emissions from both new and existing major sources. Area sources are
not being regulated under the proposed rule.
Printing, coating, and dyeing of fabrics as described in the
initial listing includes any affected source engaged in those
activities. We also have found that slashing and finishing operations
in printing, coating and dyeing sources have the potential to emit
major source levels of organic HAP. We use the product lists contained
in the NAICS code descriptions to describe the vast array of products
composed of or containing fabric, textiles, yarn, fiber, cord, or
thread that has been coated, printed, slashed, dyed or finished.
We intend the source category to include sources for which fabric
and other textiles coating, printing, slashing, dyeing and finishing is
either their principal activity or an integral part of a production
process that is the principal activity. Many coating, printing,
slashing, dyeing and finishing operations are located at plant sites
that are dedicated to these activities. However, some are located at
sites for which some other activity is principal, such as production of
sheets and towels or rubber belt manufacturing. Collocated coating,
printing, slashing, dyeing and finishing operations comparable to the
types and sizes of the dedicated affected sources, in terms of the
affected operation and applicable emission control techniques, are
included in the source category.
The source category does not include research or laboratory
facilities; janitorial, building, and facility maintenance operations;
coating, printing, slashing, dyeing, or finishing operations in which
no organic HAP-containing materials are used; or coating, printing,
slashing, dyeing or finishing used by a facility and not for commerce,
unless organic HAP emissions from the coating, printing, slashing,
dyeing or finishing operations are at major source levels.
Subcategory selection. The statute gives us discretion to determine
if and how to subcategorize. Once the floor has been determined for new
or reconstructed and existing affected sources for a source category or
subcategory, we must set MACT standards that are no less stringent than
the MACT floor. Such standards must then be met by all sources within
the source category or subcategory. A subcategory is a group of similar
sources within a given source category. As part of the regulatory
development process, we evaluate the similarities and differences
between industry segments or groups of affected sources comprising a
source category. In establishing subcategories, we consider factors
such as process operations (type of process, raw materials, chemistry/
formulation data, associated equipment, and final products); emission
characteristics (amount and type of HAP); add-on control device
applicability; and opportunities for pollution prevention. We may also
consider existing rules or guidance from States and other regulatory
agencies in determining subcategories.
After reviewing survey responses from the industry, facility site
visit reports, and information received from stakeholder meetings, we
found that the printing, coating, and dyeing of fabrics and other
textiles source category may be grouped into three subcategories with
differing material application and performance requirements, emission
characteristics, applicable add-on emission controls and pollution
prevention opportunities. The three subcategories are: (1) Coating and
printing, (2) slashing, and (3) dyeing and finishing. The following
paragraphs include descriptions of each subcategory.
Coating and printing subcategory. The coating and printing
subcategory includes affected sources that apply coatings to or print
textile substrates. The coating and printing manufacturing processes,
HAP emissions, and types of controls in use sufficiently set them apart
from the other processes that are used in the manufacture of textile
products to warrant a subcategory. Coating is a web coating operation,
and the physical operations and most sources performing coating are
separate and distinct from the other textile operations. Many coating
operations are subject to State reasonably available control technology
requirements or to the polymeric coating of supporting substrates NSPS
(40 CFR part 60, subpart VVV) and have installed emission control
systems for VOC. Since a number of the VOC emitted from
[[Page 46040]]
coating operations are also organic HAP (e.g., toluene, MEK, xylene,
and methanol), the VOC emission control systems in place are also
effective for controlling organic HAP emissions. Printing is a web
process very similar to coating and uses some of the same equipment.
The application and drying of printing materials and the organic HAP
emission sources are identical or nearly identical to coating, and,
therefore, the control options and limits for coating would be
applicable to printing as well.
Coating is a specialized chemical finishing technique designed to
produce textiles to meet high performance requirements, e.g., for end
products such as tents, roofing, soft baggage, marine fabric, drapery
linings, flexible hoses, hot-air balloons, and awnings. Coatings
generally impart elasticity to substrates, as well as resistance to one
or more elements such as abrasion, water, chemicals, heat, fire, and
oil. The substrate itself provides strength (such as tear strength) and
can include wovens, nonwovens, knits, yarn, cord, and thread, although
woven fabrics are most commonly used.
Printing is the application of color to a substrate in a design or
pattern. In some cases, the printing material is chemically the same as
coating material only thinned to a lower viscosity. There are typically
four types of printing, including rotary screen, engraved roller, flat-
bed screen, and heat transfer. Rotary screen and engraved roller
closely resemble coating and use principally the same type of equipment
as coating. Flat-bed screen is typically not a high production
technique and does not emit large quantities of HAP over a period of
time given the limits of production. Heat transfer emits little or no
HAP in the transfer of the print to the substrate.
Both the substrates coated and printed as well as the coatings
themselves vary. A number of different substrates can be coated
including rayon, nylon, polyester, cotton, and blends. Coating
chemicals used vary depending on end use of the coated substrate.
Examples of coating chemicals include vinyl, urethane, silicone, and
styrene-butadiene rubber. The polymer can be bought in various forms
such as chunks, blocks, chips, pellets or fine powder. However, besides
the polymer resins, several other chemicals can also be included in the
prepared coating. These include plasticizers to increase pliability
(e.g., fatty acids, alcohols), solvents to disperse solids and adjust
viscosity (e.g., toluene, xylene, N,N-dimethylformamide, and MEK),
pigments, curing agents, and fillers (e.g., carbon black and teflon).
Rubber coating materials are frequently compounded in the facility
performing the coating. Manmade fibers coated with epoxy or phenolic
resins are often not immediately cured following application, but are
first laid in a mold and then cured under pressure to form a composite
structure.
The coating or printing process generally is made up of the
following unit operations: mixing the coating or printing materials
(including the solvents), conditioning the substrate, applying the
coating or printing materials to the substrate, evaporating the solvent
in a drying oven and sometimes curing or vulcanizing by exposure to
heat, and cleaning coating or printing operation equipment. A coating
or printing operation with coating or printing material drying or
curing at ambient conditions is not coating or printing for the purpose
of the proposed subpart. Therefore, a coating or printing operation
that does not dry or cure the applied coating or printing material by
exposure to heat is not subject to the requirements of the proposed
subpart.
The application processes used by affected sources in the industry
are similar in that they use continuous web coating techniques, but
they include several types of coating and substrates. The coating
industry treats coating as a surface applied coating in which a
distinct layer of coating is applied to the textile surface.
Slashing subcategory. The slashing subcategory includes affected
sources that perform slashing operations. The slashing equipment,
emission characteristics, and opportunities for pollution prevention in
the industry are distinct from those in the rest of the fabric and
other textiles coating, printing, and dyeing source category,
warranting a separate subcategory.
Slashing is a yarn preparation process performed on warp yarn prior
to weaving. Warp yarns need to sustain their elongation and flexibility
during the weaving process, which necessitates the slashing process. In
the slashing process, large rolls (beams) of warp yarn are passed
through a size box containing the aqueous sizing compound. Squeeze
rolls remove excess solution and the yarn then passes through a drying
unit that usually consists of steam filled dry cans (rollers) or an
oven and then through a series of separator bars to prevent the ends
from sticking together. After the separation process, the warp is then
wound onto the loom beam. Some mills perform desizing. During the
desizing step, at the end of the textile process, most of the sizing
(slashing material) is removed from the textile by washing and the
sizing is present in the wastewater.
The objectives of slashing are to strengthen, smooth the outer
surface, and lubricate the yarn. The chemical nature of the size
applied is dependent on the yarn substrate and the type of weaving
being used. The three main types of size currently used are natural
products (starch), fully synthetic products (e.g., PVA), and
semisynthetic blends (e.g., modified starches and carboxymethyl
cellulose (CMC)).
When starch or modified starch is the sizing compound, there is
water but no HAP emitted from the slashing process. Starch is used
principally on cotton, but does not work well on synthetic fibers.
Also, starch is not more widely used and is not a good substitute for
synthetic sizing because of water pollution concerns. Starch greatly
increases the biological oxygen demand and cannot be partially
recycled.
The PVA and CMC are typically recycled when possible to reduce
water treatment and water pollution. The CMC is not as widely used as
starch and PVA because of the cost of the material. The CMC is not as
effective in the slashing process on cotton and synthetic textiles as
starch, modified starches, or PVA, respectively.
The primary source of HAP emissions from slashing is methanol from
PVA size, typically applied to synthetics (although it adheres to and
is used for natural fibers as well). The methanol is present in the PVA
size as a contaminant and is not needed for the slashing process. The
methanol emissions can arise either from the size cooking operation
and/or from the application or slashing process; the distribution is
unclear, although it will depend upon the temperature at which the size
is cooked, the cooking time, and how often mixing containers (cookers)
are opened. These processes are not presently regulated by Federal,
State or local agencies, and there are no known HAP emission capture or
add-on control systems in use on size cooking or slashing processes.
However, information submitted to us from suppliers representing
approximately 74 percent of the domestic market for PVA indicate that
PVA with less than 1 percent methanol is readily available, and these
suppliers are now changing their production to supply the lower HAP
material.
Dyeing and finishing subcategory. The dyeing and finishing
subcategory includes affected sources that perform dyeing and/or
finishing operations. The process operations, materials and the organic
HAP emissions sufficiently set these processes apart from the other
[[Page 46041]]
processes that are used in the manufacture of textile products to
warrant a subcategory. Dyeing and finishing processes both use various
types of aqueous materials, the choice of which depends on the type of
substrate and the desired properties in the end product. Many affected
sources perform both dyeing and finishing and use some common equipment
(e.g., tenter frames) for unit operations in both processes. In some
cases, the finishes are applied to the substrate wet from the dyeing
process, and no drying is done until after the finish application. No
add-on organic HAP emission controls are known to be in use on dyeing
processes and very few on finishing processes. The few add-on emission
controls used on finishing processes were installed to control opacity
and are not effective at controlling organic HAP emissions. The
similarities of process operation equipment, sources of organic HAP
emissions (many of which are fugitive), absence of add-on HAP emission
controls and opportunities for pollution prevention in the dyeing and
finishing industry lend these operations well to subcategorization for
the purpose of determining emission limits.
Dyeing is the application of color to the whole body of a textile
material with some degree of color fastness. Textiles are dyed using
continuous and batch processes, and dyeing may take place at any of
several stages in the manufacturing process (i.e., prior to fiber
extrusion, fiber in staple form, yarn, fabric, garment). Most of the
dyeing is done in finishing departments of basic manufacturing sources,
although there are also several commission dyehouses. From an
environmental perspective, dyeing has typically been viewed as a
wastewater issue due to large quantities of water, chemicals, and
auxiliaries (such as salt) used.
Dyeing is essentially a mass transfer process where the dye
diffuses in solution, adsorbs onto the fiber surface, and finally,
within the fiber. Dyeing is complicated by the fact that there are many
sources of color variations, such as dyes, substrate, preparation of
substrate, dyeing auxiliaries used, and water. Processing variables
such as time, temperature, and dye liquor ratio (lbs of dyebath to lbs
of cloth) also affect dyeing results. There are hundreds of dyes within
several dye classes, each of which exhibits different results when
applied to different types of substrates.
Various types of dyeing machines are used for both continuous and
batch processes. Every dye system has different characteristics in
terms of factors such as versatility, cost, tension of substrate, use
of carriers and weight limitations. Dyeing systems can be aqueous,
nonaqueous (inorganic solvents), or use sublimation (thermosal, heat
transfer). Hydrophilic fibers such as cotton, rayon, wool, and silk are
typically easier to dye as compared with hydrophobic fibers such as
acetate, polyesters, polyamides, and polyacrylonotriles.
The four basic steps in the dyeing process are: dissolving or
dispersing dye, diffusing dye onto the fiber surface, absorbing dye
onto the fiber surface, and diffusing dye into the fiber. Batch dyeing
involves moving the dye liquor through the goods or moving the goods
through the dye liquor. The substrate is immersed in the dyebath during
the entire period of dyeing. In batch dyeing, a certain amount of
substrate, usually 220 to 2,200 lbs, is loaded onto a dyeing machine
and is brought to equilibrium or near equilibrium with a solution
containing the dye. Once immersed in the dye bath, because the dyes
have an affinity for the fibers, the dye molecules leave the dye
solution and enter the fibers over a period of minutes to hours.
Auxiliary chemicals and controlled dyebath conditions (mainly
temperature) accelerate and optimize the action. The dye is fixed in
the fiber using heat and/or chemicals after which the substrate is
washed to remove unfixed dyes and chemicals. There is a trend to use
lower liquor ratios (lbs of dyebath to lbs of cloth) in batch dyeing,
which lends benefits such as faster heating/cooling and less waste.
Batch equipment can usually be purchased as atmospheric (operated below
212 degrees Fahrenheit) or pressurized (operated to about 280 degrees
Fahrenheit) machines. Most batch dyeing is being done using pressurized
machines, although some sources use atmospheric machines, especially
for dyeing. Atmospheric dyeing might be required for fleeces and
stretch fabrics, such as Lycra, which typically cannot be
dyed using jet equipment. Dyeing processes in pressurized machines
release no organic HAP emissions to the atmosphere since the process is
totally enclosed, and the pressure is released at the end of the dyeing
process by cooling the dye bath which is subsequently drained before
opening the dyeing machine. However, in some cases, the drying of the
pressure-dyed substrate releases HAP emissions.
Continuous processes typically consist of dye application, dye
fixation with chemicals or heat, and washing. Almost all continuous
dyeing is done at atmospheric pressure. Continuous dyeing is usually
used for long runs of polyester/cotton fabrics and involves immersing
fabrics in a relatively concentrated dyebath for short periods.
Substrate is fed continuously into a dye range at speeds usually
between 540 and 2,690 feet per minute, and a concentrated solution of
dyes and chemicals (held in pads) is moved evenly and uniformly to the
goods with thorough penetration. A pad mangle helps apply pressure to
squeeze dye solution into the fabric, and the dye is usually diffused
or fixed by heating in a steamer or oven. Dye fixation on fiber occurs
much more rapidly in continuous dyeing as compared to batch dyeing.
After fabrics are dyed, they are dried in ovens or tenter frames after
washing to remove un-reacted chemical or loose dye. A substrate that is
processed through atmospheric batch dyeing is not dried at the dye
range; it is sent to finishing and may be finished wet or dry.
Various classes of dyes can be used, e.g., disperse for synthetics
and direct for cellulosics. Dyes used in the textile industry are
mostly synthetic and are derived from coal tar and petroleum-based
derivatives. Dyes are sold as powders, granules, pastes, liquid
dispersions, and solutions. Not only are dyes applied in different
ways, they also impart color using different mechanisms. Dyes can be
classified according to chemical constitution or method of application.
Dyestuffs can work on principles of electrostatic bonding, covalent
bonding, or physical entrapment. For example, acid dyes work through
the mechanism of electrostatic bonding, whereas disperse dyes work by
physical entrapment. Different dye classes exhibit different affinities
depending on the type of fiber, although even dyes within the same
classes can show wide affinity variations. They also exhibit different
properties such as their fastness under end use conditions (e.g.,
light, laundering, or dry cleaning).
Various combinations of chemical auxiliaries and process conditions
(temperature and pressure) may be used to better fix the dye on the
textile or impart specific characteristics. For example, a dye bath may
contain the dyestuffs along with appropriate auxiliaries such as
wetting agents and also specific chemicals such as acetic acid or
sodium hydroxide. The use of higher temperatures and superatmospheric
pressures have reduced the need for dye carriers (chemical accelerants)
that were required at lower temperatures for the use of disperse dyes
on synthetic substrates, such as polyester.
The sources of HAP emissions from dyeing are the HAP constituents
that are
[[Page 46042]]
contained in dyestuffs and auxiliary chemicals as purchased. The HAP
constituents are needed to impart certain desirable characteristics to
the dyed substrate (e.g., certain colors can only be attained through
the use of HAP-containing dyestuffs or auxiliaries.) No HAP are known
to be added by the users. The fraction of HAP contained in dye
materials that are emitted to the atmosphere are generally estimated to
range from zero to 10 percent, but have been reported as high as 100
percent, and depend on the characteristics of the specific HAP
constituents and the pressures and temperatures that the HAP are
exposed to in the dyeing process operations. The fraction of HAP
emitted to the atmosphere from dye materials have not been confirmed by
test data. Most HAP constituents are believed to be rinsed from the
substrate before the substrate is dried, because drying a substrate
with unattached dye would adversely affect the quality of the dyed
product.
Finishing refers to any process operation performed after
bleaching, dyeing, or printing that improves the appearance and/or
usefulness of a textile substrate. Finishing encompasses any of several
mechanical (e.g., texturizing, napping) and chemical processes (e.g.,
optical finishes, softeners, urea-formaldehyde resins for crease
resistance) performed on fiber, yarn, or fabric to improve its
appearance, texture, or performance. The organic HAP emission sources
from finishing are specific chemical compounds that may be applied and
released during subsequent drying and curing operations. Chemical
finishing is also referred to as wet finishing. No chemicals are used
in mechanical or dry finishing.
The textile is usually dried prior to chemical finishing using
either convective (hot air) or conductive (heated cans) methods.
Chemical finishing is commonly done on a continuous finishing range
(pad and tenter frame). The textile is passed through an aqueous
solution containing the finishing chemical(s) and auxiliaries. After
treatment, the textile is typically passed through an oven to drive off
water and activate/cure finishing chemicals. It is important to note
that there is no set recipe for the chemical finishes or mechanical
finishing processes applied to any given substrate. Finishing methods
are used according to desired characteristics of the end product (which
vary widely and are market driven), and the firms themselves have some
amount of flexibility in the specific processes or chemicals they
choose to use for a particular function.
The industry uses numerous categories of proprietary chemical
speciality products that are used as chemical finishes. Some examples
of chemical finish classes include:
Resin finishes (permanent press) are used on cotton or
rayon to minimize the need to iron by keeping the fabric smooth after
washing and drying. Most resins contain formaldehyde; resins without
formaldehyde are typically much costlier and adversely affect product
quality.
Softeners are used with resins to improve the way the
fabric feels by breaking down hardness or stiffness.
Stain resist finishes are used extensively on carpets and
upholstery fabrics. Soil release finishes allow soils and stains to be
removed by laundering.
Water repellants used to prevent fabrics from being wet
out (breathable, unlike waterproofing agents) include, but are not
limited to, wax, silicone, and fluorine.
Flame retardant qualities can be achieved by using special
fibers or phosphorus-based finishes.
Antistatic agents decrease or eliminate static electricity
in textiles.
Handbuilders give the fabrics body or stiffness. Other
examples of types of chemical finishes include anticreasing agents,
deodorants, moth resisting agents, oil repellants, rust preventatives,
and shrinkage controllers. Some companies use more specialized finishes
like electrical finishes and teflon. Because there are
typically a wide variety of choices of chemical finishes that can be
used within each finish class, it is often difficult to tag finishes
used in certain classes as always toxic or nontoxic. In certain cases,
as in the case of permanent press finishes, most of the resins used
contain formaldehyde, although low or non-formaldehyde finishes are
being developed to suit certain applications.
There are also several different types of mechanical finishing
techniques. For example, heatsetting can be done to improve dimensional
stability in synthetic textiles. Shearing involves using rotary
blade(s) to trim raised surfaces and reduce pilling. Other examples
include embossing, glazing, sueding, and polishing.
Many chemical and mechanical alternatives are available for every
finishing operation, but the specific nature and applicability of these
is unclear. Some mechanical finishes and design alternatives can avoid
chemical processing. For example for softness, enzyme softening of
cotton and other mechanical alternatives can be used. Proper use and
application of N-methylol crosslinkers can minimize formaldehyde
releases. Mechanical finishing (compacting) can also eliminate use of
the crosslinker. Some crosslinkers that eliminate formaldehyde are
available, but much more expensive. The industry has made a lot of
efforts to reduce the amount of free formaldehyde in resins, however
good substitutes that do not adversely affect the quality of the
product are difficult to find. Formaldehyde contents can vary anywhere
from less than one half of one percent for light weight fabrics to 4
percent for heavy fabrics (melamine-formaldehyde resins), and there is
a lot of variability in types of resins. Formaldehyde itself does not
affect the product, however it does affect the properties of the resin
itself (manufacturing). Acrylic handbuilders and stiffeners can replace
formaldehyde-based handbuilders.
The sources of organic HAP emissions from finishing are the HAP
constituents that are contained in finishing materials as purchased. As
is the case with dyeing, the organic HAP constituents are needed to
impart certain desirable characteristics to the finished substrate
(e.g., a resin finish containing organic HAP might be applied to a
cotton/polyester blend for durable press and dimensional stability). No
organic HAP are known to be added by the users. In finishing, unlike in
dyeing, the fraction of organic HAP contained in finishes that are
emitted to the atmosphere are generally assumed to be 100 percent with
the exception of HAP that cross-link to the fiber, such as
formaldehyde. This is because the finished textile is typically dried
and cured at relatively high temperatures over 300 degrees Fahrenheit.
B. How did We Select The Regulated Pollutants?
Organic HAP. Available emission data collected during the
development of the proposed NESHAP show that the primary organic HAP
emitted from printing, coating and dyeing sources include toluene, MEK,
methanol, xylenes, MIBK, methylene chloride, n-hexane,
trichloroethylene, and n,n-dimethylformamide. These compounds account
for approximately 81 percent of this category's nationwide organic HAP
emissions. However, many other organic HAP are used, or can be used, in
coating, printing, slashing, dyeing, and finishing operations.
Therefore, the proposed rule would regulate emissions of all organic
HAP.
Inorganic HAP. Based on information reported during development of
the proposed NESHAP, inorganic HAP
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contained in the coating, printing, dyeing and finishing materials used
by this source category include chromium, cobalt, hydrogen chloride,
lead, manganese compounds and nickel. There is limited opportunity for
these HAP to be emitted into the ambient air because all of the
application techniques used involve direct application of the inorganic
HAP-containing material to the substrate by techniques such as knife-
over-roll, reverse roll, dip, pad and immersion. These techniques would
not typically generate air emissions of the inorganic compounds. Once
deposited on the substrate, the inorganic compounds remain on the
substrate and are not emitted during subsequent drying and curing
process operations. Therefore, we conclude that there are limited or no
air emissions of inorganic HAP, and the proposed standards would not
regulate them.
C. How Did We Select the Affected Source?
In selecting the affected source(s) for emission standards, our
primary goal is to ensure that MACT is applied to HAP-emitting
operations or activities within the source category or subcategory
being regulated. The affected source also serves to establish where new
source MACT applies under a particular standard. Specifically, the
General Provisions in subpart A of 40 CFR part 63 define the terms
``construction'' and ``reconstruction'' with reference to the term
``affected source'' and provide that new source MACT applies when
construction or reconstruction of an affected source occurs. The
collection of equipment and activities evaluated in determining MACT
(including the MACT floor) is used in defining the affected source.
When an emission standard is based on a collection of emissions
sources, or total facility emissions, we select an affected source
based on that same collection of emission sources, or the total
facility, as well. This approach for defining the affected source
broadly is particularly appropriate for industries where a plantwide
emission standard provides the opportunity and incentive for owners and
operators to utilize control strategies that are more cost effective
than if separate standards were established for each emission point
within an affected source.
Selection of affected source. The affected source for the proposed
standards is broadly defined for each subcategory. It includes all
operations associated with coating and printing, with slashing, or with
dyeing and finishing and in all cases includes the cleaning of process
operation equipment. These operations include storage and mixing of
regulated materials, regulated material application and flash-off and
drying and curing of applied materials by exposure to heat, cleaning
operations, waste handling operations, and wastewater treatment
operations.
In selecting the affected source, we considered, for each
operation, the extent to which HAP-containing materials are used and
the amount of HAP that are emitted. Coating, printing, slashing, dyeing
and finishing material application, flash-off, and curing/drying
operations by exposure to heat account for the majority of HAP
emissions from coating, printing, slashing, dyeing and finishing
operations. These operations are included in the affected source.
We were not able to obtain data to adequately quantify HAP
emissions from storage, mixing, cleaning, waste handling and wastewater
treatment. However, solvents that are added to coatings as thinners,
for example, and HAP from other HAP-containing materials such as dyeing
or finishing auxiliaries, may be emitted during mixing and storage. The
level of emissions depends on the type of mixing and the type of
storage container and the work practices used at the affected source.
The magnitude of emissions from cleaning depends heavily on the amount
and HAP content of cleaning materials used. Emissions from waste
handling operations depend on the type of system used to collect and
transport organic HAP-containing waste materials in the affected
source. For example, solvent-laden rags that are used to clean
application equipment could be a source of HAP emissions. The method
used to isolate and store such rags affects the level of emissions to
ambient air. The HAP emissions from wastewater treatment depend on the
quantity and types of HAP discharged to the wastewater treatment
operation and the subsequent wastewater treatment processes, e.g.,
treatment by aeration or by biodegradation. Mixing, storage, cleaning,
waste handling, and wastewater treatment operations are included in the
affected source.
A broad definition of the affected source was selected to provide
maximum flexibility in complying with the proposed emission limits for
organic HAP. In planning its total usage of HAP-containing materials,
each affected source can select among available coating, printing,
slashing, dyeing, finishing, thinning, and cleaning materials, as well
as use of emission capture systems and add-on controls for coating and
printing operations, to maximize emissions reductions in the most cost-
effective manner.
Additional information on the coating, printing, slashing, dyeing
and finishing operations is included in the docket for the proposed
standards.
D. How Did We Determine the Basis and Level of the Proposed Standards
for Existing and New or Reconstructed Sources?
The sections below present the rationale for determining the MACT
floor, regulatory alternatives beyond the floor, and selection of the
proposed standards for existing and new or reconstructed affected
sources in each of the three subcategories identified in the Printing,
Coating, and Dyeing of Fabrics and Other Textiles source category.
How did we determine the MACT floor technology? After we identify
the specific source categories or subcategories of sources to regulate
under section 112 of the CAA, we must develop emission standards for
each category and subcategory. Section 112(d)(3) establishes a minimum
baseline or ``floor'' for standards. For new sources in a category or
subcategory, the standards cannot be less stringent than the emission
control that is achieved in practice by the best-controlled similar
source. The standards for existing sources can be less stringent than
standards for new sources, but they cannot be less stringent than the
average emission limitation achieved by the best-performing 12 percent
of existing sources (or the best-performing five sources for categories
or subcategories with fewer than 30 sources).
Coating and printing subcategory. There are an estimated 60
facilities in the coating and printing subcategory. Quantitative data
on HAP use and emission control were obtained from 22 coating sources.
The 22 sources in the MACT database are representative of the different
sizes of companies and the range of products in the national population
of coating sources. Qualitative data providing descriptions of coating
and printing processes, HAP control technologies, and process and
control technology concerns also were obtained from site visits and
industry trade groups, such as the Rubber Manufacturers Association.
These data verified that the coating processes and HAP emission sources
are similar for all coating types and that similar HAP control
technologies are used. They also verified that, although we do not have
quantitative data on printing operations, it is reasonable to use the
coating data for making decisions for both coating and printing sources
due to the
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similarities between coating and printing processes and materials used.
The MACT database shows that the most common approach for reducing
organic HAP emissions at coating and printing sources is the use of
add-on capture and control systems. At the sources reporting the
highest level of control, coating application stations are enclosed in
rooms, and the ventilation air is directed to the add-on control
device. This type of capture system can achieve 100 percent capture of
emissions when designed to meet the criteria specified in EPA Method
204 of 40 CFR part 51, appendix M. This capture system is called a PTE.
Of the 22 sources in the MACT database, six reported the use of PTE and
13 reported that they operated control devices on a total of 29 coating
lines. Of the 29 controlled lines, 16 lines use thermal oxidizers,
three lines use catalytic oxidizers, nine lines use carbon adsorbers,
and one line uses an electrostatic precipitator.
The MACT database contains information concerning the level of HAP
emissions from coating application and drying/curing, the capture
efficiency for each coating application area or for the entire coating
line, and the destruction or removal efficiency of the add-on control
device receiving the HAP emissions. We were able to determine the
coating line application and drying/curing OCE for each source from
this information when available. This value was the most common among
all the data available, and it was determined that the coating
application and drying/curing OCE was the value that was most
correlated with HAP emissions. Therefore, the coating application and
drying/curing OCE was used as the basis for the MACT floor
calculations. The OCE was calculated as a sourcewide average to
incorporate the effects of averaging across coating lines in sources
with more than one coating line.
To determine the existing source MACT floor, the sources were
ranked based on the average OCE. The statute requires EPA to base the
floor for existing sources on the average emission limitation achieved
by the best performing 12 percent of existing sources for which the
Administrator has data. The best performing 12 percent of the 22
sources in the MACT database constitutes a set of three affected
sources. All three of the best-performing sources use capture systems
and add-on control devices including both thermal oxidizers and carbon
adsorbers. The two sources using thermal oxidizers are achieving 100
percent capture of application station emissions through the use of
PTE. The reported OCE for the top three sources ranged from 93 to 99
percent. These data clearly indicate that controls on some specific
coating operations may be capable of achieving greater than 99 percent
HAP destruction based on 100 percent capture and thermal oxidizer
destruction efficiency greater than 99 percent. However, to determine
the level of emission control that is technically and consistently
achievable over the long term with thermal oxidation, it is important
to consider not only the level of control reported, but also the data
quality concerns and the control levels that EPA has generally found to
be achievable for this type of control technology. This approach
ensures that factors that affect control levels, such as variations in
source operating conditions and inlet loadings to the add-on control
device, are accommodated in the determination of the MACT floor.
A study conducted by EPA indicated that a 98 percent reduction is
the minimum control efficiency that new thermal oxidizers can be
expected to achieve. Information from vendor guarantees supports the
determination of a destruction efficiency of 98 percent for thermal
oxidizers. Therefore, we adjusted the destruction efficiencies for the
two MACT floor sources using thermal oxidizers to 98 percent. The
calculated MACT floor using the adjusted value results in an average 97
percent OCE for the three sources that make up the best-performing 12
percent of sources in the coating and printing subcategory. Therefore,
the MACT floor for existing sources is 97 percent OCE.
As indicated previously in this preamble, the MACT floor for new
sources must reflect the emission control achieved in practice by the
best-controlled similar source. The OCE data cited above show that the
best-controlled similar source for which we have data is using a PTE to
achieve 100 percent capture and a thermal oxidizer, which as described
above, we have determined can consistently achieve 98 percent
destruction. Therefore, a 98 percent OCE is the MACT floor for new and
reconstructed sources in the coating and printing subcategory.
Data from the coating MACT database were used to calculate
alternative emission rate limits for existing and new and reconstructed
sources. The alternative organic HAP emission rate was calculated based
on applying the MACT floor OCE (97 percent for existing sources and 98
percent for new and reconstructed sources) to a pre-controlled HAP
emission rate representative for this industry. This calculation
process, described in the docket, resulted in HAP emission rates of
0.12 lb of organic HAP per lb of solids for existing sources and 0.08
lb of organic HAP per lb of solids for new and reconstructed sources.
The alternative emission rate limits are being proposed to provide
compliance flexibility for affected sources.
Slashing subcategory. As has been previously noted in this
preamble, the primary source of HAP emissions from slashing is methanol
from PVA size. The methanol emissions can arise either from the size
cooking operation, the application process, or both; the distribution
is unclear. Also as previously noted, there are no known HAP emission
capture or control systems in place on size cooking or slashing
processes. Therefore, we judged that the most reasonable approach to
establishing a MACT floor would be to identify a pollution prevention
option that is the average being achieved by all affected slashing
operations.
Based on information submitted to the EPA by the American Textile
Manufacturers Institute (ATMI) on September 17, 1999, we determined
that the majority, not just the top 12 percent, of the domestic textile
market in 1998 was using PVA for slashing with methanol comprising less
than 1 percent by weight of the PVA ``as purchased.'' Methanol is a
contaminant in the PVA that is a residual material from the manufacture
of the PVA. Prior to 1999, the typical PVA sizing compound contained
from 4 to 10 percent methanol. The |